This article examines Maria F. Karlova's relatively unknown travelogue about her visit to Ottoman Macedonia and Albania in 1868. She was a sister of the prominent Slavist scholar and diplomat Alexander F. Gil'ferding and traveled with him. She appears to be the only known Russian female traveler to publish a travelogue about the Ottoman Balkans until the late 1870s. Karlova constructs her gender identity through elite lenses against three principal backdrops: the Turkish province, Europe, and Russia. She offers an example of how gender and class can be inserted into discourses about Russian identity and Russia's place in Europe's symbolic map of modernity. She also introduces gender issues into debates about Russia's political interests and Slavophile views about the Balkans. This article argues that Karlova asserts her sense of belonging to European elite culture in order to raise the issue of women's emancipation. The travelogue provides insights into the process of gender construction in Russia. The intertwined themes of gender, class, and national identity are compared to contemporaneous Victorian women's travelogues.